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VANADOCENE DICHLORIDE MSDS报告

MSDS目录

化学品及企业标识

PRODUCT NAME

VANADOCENE DICHLORIDE

NFPA

Flammability 1
Toxicity 3
Body Contact 0
Reactivity 1
Chronic 2
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

PRODUCT USE

Intermediate.

SYNONYMS

C10-H10-Cl2-V, dichlorovanadacene, "vanadium, dichlorodi-pi-cyclopentadienyl-",
"dicyclopentadienyl-vanadium dichloride", bis(cyclopentadienyl)vanadium

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Toxic if swallowed.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  Toxic effects may result from the accidental ingestion of the material; animal experiments indicate that ingestion of less than 40 gram may be fatal or may produce serious damage to the health of the individual.  Vanadium poisoning causes immediate distress with nose bleeds, severe diarrhea, paralysis of the legs, breathing difficulties, convulsions and death. The liver and kidneys may degenerate, and sometimes there can be bleeding from the lung and adrenal cortex. Vanadium is about as toxic as arsenic.  

EYE

  Although the material is not thought to be an irritant, direct contact with the eye may cause transient discomfort characterized by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result. The material may produce foreign body irritation in certain individuals.  

SKIN

  Skin contact is not thought to produce harmful health effects (as classified using animal models). Systemic harm, however, has been identified following exposure of animals by at least one other route and the material may still produce health damage following entry through wounds, lesions or abrasions. Good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.  Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.  

INHALED

  Inhalation of dusts, generated by the material during the course of normal handling, may be damaging to the health of the individual.  The material is not thought to produce respiratory irritation (as classified using animal models). Nevertheless inhalation of dusts, or fume, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.  The inhalation of vanadium dust can cause irritation of the respiratory tract and eyes, with cough, wheezing, bronchitis, phlegm with blood stains, and blackening of the tongue. Internal symptoms may include loss of appetite, anemia, nausea, headache, sleep difficulties, nervousness, dizziness, kidney damage, tremor, psychic disturbances and blindness.  

CHRONIC HEALTH EFFECTS

  Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis; caused by particles less than 0.5 micron penetrating and remaining in the lung. Prime symptom is breathlessness; lung shadows show on X-ray.  Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.  There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.  Vanadium is an essential trace element. Poisoning can cause stomach upset,emphysema and wheezing.  

成分及组成信息

危险性质描述

急救措施

消防措施

泄露应急处理

处理和储存

接触控制

理化特性

稳定性和反应活性

毒理学信息

生态学资料

废弃处理

运输信息

法规信息

其他信息