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HEXYLLITHIUM MSDS报告

MSDS目录

成分及组成信息

危险性质描述

急救措施

消防措施

泄露应急处理

处理和储存

接触控制

理化特性

稳定性和反应活性

毒理学信息

生态学资料

废弃处理

运输信息

法规信息

其他信息

化学品及企业标识

PRODUCT NAME

HEXYLLITHIUM

NFPA

Flammability 3
Toxicity 2
Body Contact 4
Reactivity 2
Chronic 2
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

PRODUCT USE

Laboratory reagent; polymerises isoprene and butadiene; intermediate in the preparation of
lithium hydride; component of rocket fuel; metalating agent.

SYNONYMS

C6-H13-Li, Li(CH2)5CH3, "hexyl lithium", n-hexylithium, n-hexylithium, 1-hexyllithium, 1-
hexyllithium, 1-lithiohexane, 1-lithiohexane

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISK

Spontaneously flammable in air.
Causes severe burns.
Risk of serious damage to eyes.
Reacts violently with water liberating extremely flammable gases.
May cause fire.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

  The material can produce severe chemical burns within the oral cavity and gastrointestinal tract following ingestion.  Considered an unlikely route of entry in commercial/industrial environments.  Lithium, in large doses, can cause dizziness and weakness. If a low salt diet is in place,  kidney damage can result. There may be dehydration, weight loss, skin effects and thyroid disturbances. Central nervous system effects include slurred speech, blurred vision, numbness, inco-ordination and convulsions. Repeated exposure can cause diarrhea, vomiting,  tremor, muscle jerks and very brisk reflexes.  

EYE

  The material can produce severe chemical burns to the eye following direct contact. Vapors or mists may be extremely irritating.  If applied to the eyes, this material causes severe eye damage.  

SKIN

  The material can produce severe chemical burns following direct contactwith the skin.  

INHALED

  If inhaled, this material can irritate the throat andlungs of some persons.  Inhalation of quantities of liquid mist may be extremely hazardous, even lethal due to spasm, extreme irritation of larynx and bronchi, chemical pneumonitis and pulmonary edema.  

CHRONIC HEALTH EFFECTS

  Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapors especially at higher temperatures.  Lithium compounds can affect the nervous system and muscle. This can cause tremor, inco-  ordination, spastic jerks and very brisk reflexes. They may cause birth defects and should not be used when pregnancy is suspected. They are effective in treating manic episodes of bipolar disorder. Restricting sodium in the diet increases the risks of taking lithium.